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    Organize by EPA Centre, University
    of California, Los Angeles, City
    University of Hong Kong 
      
      
    Training Course on 
    Reliability of Pb-free Solder Joint  
    in Advanced Electronic Packaging
    Technology 
      
      
    The rapid growth in wireless, portable, and
    multi-functional devices has enhanced the development of electronic
    packaging technology.?There is a
    greater demand of flip chip assembly in advanced packaging, especially the
    use of?Pb-free solder joints.?European Union Congress has a ban on
    Pb-based solders in consumer electronic products on July 1st,
    2006.?The reliability of Pb-free
    solder joins is of concern in manufacturing industry.?For example, the reflow of Pb-free solder
    paste produces many more residue voids than SnPb solder paste.?This one-day course will start from the
    trend in electronic packaging technology.?
    It will be followed by the analysis of solder reactions in wetting
    and in solid state aging.?The unique
    reliability behavior of spalling of intermetallic compounds in thin film
    under-bump-metallization and the formation of Kirkendall voids in thick
    under-bump-metallization will be discussed.?
    Next, electromigration induced failure in flip chip solder joints
    will be analyzed.?The unique failure
    mode of electromigration in flip chip solder joints will be explained on
    the basis of current crowding.?Joule
    heating that leads to melting of flip chip solder joints will be discussed.?Thermomigration in solder joints will be
    covered.?Then, mechanism and
    prevention of spontaneous Sn whisker growth on Pb-free finish will be
    presented.?Spontaneous Sn whisker
    growth is an irreversible process, in which there are two atomic fluxes
    driven by two driving forces.?We
    must decouple the two driving forces or the two atomic fluxes in order to
    prevent Sn whisker growth.? Due to
    accidental and frequent drops of portable devices to the ground, impact
    test has recently received much attention from the point of view of reliability
    of handheld and portable devices?A
    mini impact test machine which has been built to detect the
    ductile-to-brittle transition in ball-grid-array solder joints will be
    described.? Finally, the trend of
    miniaturization and the prospect of using nano structured materials in
    future electronic packaging technology will be discussed. 
      
    
     
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       Course Content: 
        
                
      Introduction
      - Trend of electronic packaging technology  
                
      Solder
      joint reactions  
                
      Electromigration
      in flip chip solder joints - I  
                
      Electromigration
      and thermomigration in flip chip solder joints -II  
                
      Spontaneous
      Sn whisker growth  
                
      Impact
      test of ductile-to-brittle transition in solder joints  
                
      Conclusion
      ?Nanostructured materials for electronic packaging  
        
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       Date:  
      Time:?  
      Venue: 
        
        
        
      Language: 
      Course Fee: 
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       3 January 2006 (Tuesday) 
      9.00am ?5.30pm 
      G6302, 6/F, Lift 7,Academic Building,
      City University of HK,  
      83 Tat Chee Avenue,  
      Kowloon Tong, Hong Kong 
      English  
      HK$800 per person 
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    Speaker: Professor
    King-Ning Tu received his
    Ph. D. degree in Applied Physics from Harvard University in 1968.?He spent 25 years at IBM T. J. Watson
    Research Center as Research Staff Member in Physical Science
    Department.?During that period, he
    also served as Senior Manager of Thin Film Science Department and Materials
    Science Department for 10 years.?In
    September 1993, he joined the Dept. of Materials Science and Engineering at
    UCLA as full professor.?He was
    chairman of the Department for six years from 1998 to 2004.?He is a Fellow of American Physical
    Society, The Metallurgical Society (TMS), and an Overseas Fellow of
    Churchill College, Cambridge University, UK.?He was president of Materials Research
    Society in 1981. He received the Application to Practice Award from TMS in
    1988, and Humboldt Award for US Senior Scientists in 1996.?He has been elected a member of Academia
    Sinica, Republic of China in 2002.?
    He has over 350 journal publications, edited 13 proceedings, and
    co-authored a textbook on “Electronic thin Film Science,?published by
    Macmillan in 1992.?His research
    interests are in metal-silicon reactions, solder reactions, nanoscale
    reactions, polarity effect of electromigration on interfacial reactions,
    and kinetic theories of interfacial reactions. His website is
    http://www.seas.ucla.edu/eThinFilm/. 
      
      
    A Short Course 
    on 
    "Diffusion
    and Reactions in Thin Films"
    K. N. Tu 
    Dept. of Materials Science & Engineering, UCLA 
    Los Angeles, CA 90095-1595 
    (website: http://www.seas.ucla.edu/eThinFilm/) 
    
    
     
     
     
     
     
    Basic Diffusion in Thin Films 
    K. N. Tu 
    Dept. of Materials Science & Engineering, UCLA 
    (3 hours) 
    1.    
    Macroscopic picture of diffusion: 
    Flux equation, continuity equation, growth equation
    2.    
    Microscopic picture of diffusion: 
    Exchange frequency of vacancy jumps 
    Activation enthalpies  
    Pre-factor in diffusion coefficient
    3.    
    Driving forces of diffusion:  
    Various chemical potential gradients 
    4.    
    Diffusion in a man-made superlattice  
    a. Homogenization of a periodic structure  
    b. Cahn and Hilliard's 4th order diffusion equation and solution 
    5.    
    Grain boundary diffusion 
    a. Fisher's solution 
    b. Whipple and Suzuki's solutions 
    c. GB penetration by IMC formation 
    d. Diffusion along a moving GB: DIGM
    Go Back to
    the Top 
     
     
     
     
     
    Electromigration in VLSI Interconnect 
    K. N. Tu 
    Dept. of Materials Science & Engineering, UCLA 
    (3 hours) 
    1.    
    Introduction - Historical events 
    2.    
    Electron wind force on atomic diffusion 
    3.    
    Kinetics of electromigration 
    4.    
    Effect of stress on electromigration
    5.    
    Effect of solute on electromigration 
    6.    
    Effect of current crowding on electromigration
    7.    
    Polarity effect of electromigration on contact reaction
    at cathode and anode
    8.    
    MTTF in Al and Cu metallization
    9.    
    Electromigration in solder alloys and flip chip solder
    joints
    Go Back to
    the Top 
     
     
     
     
     
    Silicide Formation in Metal Contact to
    Si 
    K. N. Tu 
    Dept. of Materials Science & Engineering, UCLA 
    (3 hours) 
    1.    
    Introduction - Historical development of
    back-end-of-line
    2.    
    Metrology of silicide formation
    3.    
    A survey of metal-Si reactions 
    a. Near-noble metal silicides 
    b. Transition metal silicides 
    c. Rare-earth metal silicides 
    d. Silicide formation on SOI 
    4.    
    Kinetics of metal-Si reactions 
    a. Diffusion-controlled and interfacial-reaction-controlled growth  
    b. Single phase formation 
    c. Solid phase amorphization
    5.    
    Electrical properties of silicide 
    a. Schottky barrier on n-type and p-type Si 
    b. Conductivity 
    c. Contact resistance
    Go Back to
    the Top 
     
     
     
     
     
    Solder Reaction in Flip Chip Technology
     
    K. N. Tu 
    Dept. of Materials Science & Engineering, UCLA 
    (3 hours) 
    1.    
    Introduction - IBM C4 flip chip technology
    2.    
    Metallurgical reliability issues in direct chip
    attachment to organic substrates
    3.    
    Wetting reaction on bulk and thin film Cu 
    a. Ripening-controlled reaction 
    b. Spalling of IMC 
    c. Wetting along V-grooves
    4.    
    Comparison of wetting reaction and solid state aging
    between SnPb solder and Cu 
    a. Ternary phase diagrams of SnPbCu 
    b. Morphology of IMC formation 
    c. Kinetics of IMC formation
    5.    
    Wetting reaction and solid state aging on bulk and thin
    film Ni, Pd, and Au 
    a. Electroless Ni(P) & Cu/Ni(V)/Al UBM 
    b. Ultra-fast IMC formation on Pd 
    c. Ultra-fast dissolution on Au
    6.    
    Pb-free solder - UBM reactions
    7.    
    Morphology and kinetics of growth of Sn whiskers
    Go Back to
    the Top 
     
     
     
    The objectives
    of this course are to offer 
    1. Basic understanding of atomic diffusion and
    diffusion related phenomena in thin films. 
     
    2. Kinetic analysis of microstructure changes in thin films under multiple
    driving forces. 
     
    3. Insight into yield and reliability issues in Al and Cu interconnects,
    silicide contacts, and flip chip solder joints.  
    Part
    of this short course has been given at MRS meetings (11/91, 11/93), Hong
    Kong University of Science and Technology (11/96), Max-Planck Institute of
    Microstructure Physics at Halle (7/97), National University of Singapore
    (1/98), Helsinki University of Technology (8/00).
    Go Back to
    the Top 
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